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Chilli peppers are hotter than most cayenne peppers, having 50,000 to 100,000 Scoville heat units. They are usually sold green in grocery stores, although if you check Google Images it will show up red.

Chili Pepper
Chilli peppers
Chilli peppers
Scoville Scale 50,000 - 100,000 SHU
Color Red, Yellow, Green
Shape Slightly Wrinkled